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Smart 1 will shed light on Earth's only natural satellite.
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European spacecraft Smart 1 is at the Moon's gateway, the region beyond which the probe is tugged more strongly by lunar gravity than by the Earth's, BBC News Online said.
Dr. Bernard Foing, chief scientist at the European Space Agency said the landmark was of symbolic importance.
On the night of Monday 15 November, Smart 1 will begin delicate maneuvers to bring it into orbit around the Moon.
Once captured by the Moon's gravity, it begins to spiral closer to the lunar surface until reaching its final orbit.
The probe will begin braking on Monday when it reaches a distance of about 50,000km. The ion engine will then fire continuously for four days as the spacecraft begins its inexorable spiral towards the Moon.
Eventually it will reach a stable elliptical orbit where it will range between 3,000km and 300km from the moon's surface.
Smart 1 will test a highly efficient solar-electric propulsion system as one of its key mission objectives.
The engine works by expelling a beam of charged xenon atoms--ions--from the back of the probe.
This produces thrust in the opposite direction, pushing the spacecraft forward. The energy to feed the system comes from the solar panels, hence the term "solar-electric".
When it begins its scientific investigations in January 2005, Sm carries an X-ray spectrometer called D-CIXS which will comprehensively map chemical elements on the Moon's surface. This will help scientists test theories of its birth and evolution.
"We believe that the Moon is the daughter of the Earth and it was created [4.5 billion years ago] when a planetary embryo the size of Mars impacted the Earth," Dr Foing explained.
"This sent some mantle of the Earth into orbit and the debris re-condensed to form the Moon."
Conversely, studying the Moon's origins and evolution could also shed light on the composition of the early Earth.
One target for D-CIXS is the biggest impact crater in the Solar System - a massive hole in the Moon more than 2,000 miles across on its far side.
By looking down the hole, it should be possible to analyze the composition of rocks deep within the Moon's interior.